• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

（E）-N'-[（2-羟基萘-1-基）亚甲基]-4-甲基苯磺酰肼

(E)-N'-[(2-Hy-droxy-naphthalen-1-yl)methyl-idene]-4-methyl-benzene-sulfono-hydrazide.

作者信息

Shahverdizadeh Gholam Hossein, Bikas Rahman, Eivazi Maryam, Mahboubi Anarjan Parisa, Notash Behrouz

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Feb 26;67(Pt 3):o713. doi: 10.1107/S1600536811006088.

DOI:10.1107/S1600536811006088
PMID:21522456
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3052163/
Abstract

In the title compound, C(18)H(16)N(2)O(3)S, the dihedral angle between the planes of the benzene ring and the naphthyl ring system is 83.37 (10)°. An intra-molecular O-H⋯N hydrogen bond occurs. Inter-molecular N-H⋯O hydrogen bonds stabilize the crystal structure. There is a π-π inter-action between the naphthyl ring systems [centroid-centroid distance = 3.7556 (15) Å]. In addition, naphth-yl-tolyl and naphth-yl-naphthyl C-H⋯π inter-actions are observed.

摘要

在标题化合物C(18)H(16)N(2)O(3)S中，苯环平面与萘环体系平面之间的二面角为83.37 (10)°。存在分子内O-H⋯N氢键。分子间N-H⋯O氢键使晶体结构得以稳定。萘环体系之间存在π-π相互作用[质心-质心距离 = 3.7556 (15) Å]。此外，还观察到萘基-甲苯基和萘基-萘基的C-H⋯π相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13ff/3052163/0ea99d40d1f1/e-67-0o713-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13ff/3052163/a6a00394bc4b/e-67-0o713-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13ff/3052163/ff2e6b8c7371/e-67-0o713-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13ff/3052163/0ea99d40d1f1/e-67-0o713-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13ff/3052163/a6a00394bc4b/e-67-0o713-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13ff/3052163/ff2e6b8c7371/e-67-0o713-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13ff/3052163/0ea99d40d1f1/e-67-0o713-fig3.jpg

相似文献

1
(E)-N'-[(2-Hy-droxy-naphthalen-1-yl)methyl-idene]-4-methyl-benzene-sulfono-hydrazide.（E）-N'-[（2-羟基萘-1-基）亚甲基]-4-甲基苯磺酰肼
Acta Crystallogr Sect E Struct Rep Online. 2011 Feb 26;67(Pt 3):o713. doi: 10.1107/S1600536811006088.
2
Crystal structures of (E)-N'-(2-hy-droxy-5-methyl-benzyl-idene)isonicotinohydrazide and (E)-N'-(5-fluoro-2-hy-droxy-benzyl-idene)isonicotinohydrazide.（E）-N'-（2-羟基-5-甲基亚苄基）异烟肼和（E）-N'-（5-氟-2-羟基亚苄基）异烟肼的晶体结构
Acta Crystallogr E Crystallogr Commun. 2016 Jun 17;72(Pt 7):980-3. doi: 10.1107/S2056989016009762. eCollection 2016 Jul 1.
3
2-(8-Bromo-imidazo[1,2-a]pyridin-2-yl)-N'-[(E)-4-diethyl-amino-2-hy-droxy-benzyl-idene]acetohydrazide dihydrate.2 -（8 - 溴 - 咪唑并[1,2 - a]吡啶 - 2 - 基）- N'-[（E）- 4 - 二乙氨基 - 2 - 羟基 - 亚苄基]乙酰肼二水合物
Acta Crystallogr Sect E Struct Rep Online. 2012 Mar 1;68(Pt 3):o816-7. doi: 10.1107/S160053681200685X. Epub 2012 Feb 24.
4
N'-[(2-Hy-droxy-naphthalen-1-yl)methyl-idene]-4-nitro-benzohydrazide.N'-[(2-羟基萘-1-基)亚甲基]-4-硝基苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2011 Dec 1;67(Pt 12):o3278. doi: 10.1107/S1600536811045685. Epub 2011 Nov 12.
5
(E)-N'-[(2-Hy-droxy-naphthalen-1-yl)methyl-idene]-4-methyl-benzohydrazide.（E）-N'-[（2-羟基萘-1-基）亚甲基]-4-甲基苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):o964. doi: 10.1107/S160053681101035X. Epub 2011 Mar 26.
6
3-Chloro-N'-[(2-hy-droxy-naphthalen-1-yl)methyl-idene]benzohydrazide.3-氯-N'-[(2-羟基萘-1-基)亚甲基]苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2011 Jan 12;67(Pt 2):o373. doi: 10.1107/S1600536811000912.
7
N'-[(E)-1-(3,5-Dichloro-2-hy-droxy-phen-yl)ethyl-idene]-4-meth-oxy-benzo-hydrazide monohydrate.N'-[(E)-1-(3,5-二氯-2-羟基苯基)亚乙基]-4-甲氧基苯甲酰肼一水合物
Acta Crystallogr Sect E Struct Rep Online. 2010 Sep 30;66(Pt 10):o2667. doi: 10.1107/S1600536810038328.
8
(E)-N'-[(2-Hy-droxy-1-naphthalen-1-yl)methyl-idene]-3-methyl-benzohydrazide.（E）-N'-[（2-羟基-1-萘-1-基）亚甲基]-3-甲基苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2011 Apr 1;67(Pt 4):o965. doi: 10.1107/S1600536811010361. Epub 2011 Mar 26.
9
1-(2-Benzoyl-1-phenyl-eth-yl)-4-[(2-hy-droxy-1-naphth-yl)methyl-idene-amino]-3-phenyl-1H-1,2,4-triazole-5(4H)-thione.1-（2-苯甲酰基-1-苯基-乙基）-4- [（2-羟基-1-萘基）亚甲基氨基]-3-苯基-1H-1,2,4-三唑-5（4H）-硫酮
Acta Crystallogr Sect E Struct Rep Online. 2011 Feb 19;67(Pt 3):o675. doi: 10.1107/S1600536811005721.
10
2-Hy-droxy-N'-(5-hy-droxy-2-nitro-benzyl-idene)-3-methyl-benzohydrazide.2-羟基-N'-(5-羟基-2-硝基亚苄基)-3-甲基苯甲酰肼
Acta Crystallogr Sect E Struct Rep Online. 2012 Mar 1;68(Pt 3):o559. doi: 10.1107/S1600536812002437. Epub 2012 Feb 4.

引用本文的文献

1
N'-[(E)-2-Hy-droxy-5-iodo-benzyl-idene]-4-methyl-benzene-sulfono-hydrazide.N'-[(E)-2-羟基-5-碘苄叉基]-4-甲基苯磺酰肼
Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):o2760. doi: 10.1107/S1600536812035738. Epub 2012 Aug 23.

本文引用的文献

1
(2Z,N'E)-N'-[(2-Hy-droxy-1-naphth-yl)methyl-idene]furan-2-carbohydrazonic acid.
Acta Crystallogr Sect E Struct Rep Online. 2010 Jul 21;66(Pt 8):o2073. doi: 10.1107/S1600536810027935.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.