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(E)-N'-[(2-羟基萘-1-基)亚甲基]-4-甲基苯磺酰肼

(E)-N'-[(2-Hy-droxy-naphthalen-1-yl)methyl-idene]-4-methyl-benzene-sulfono-hydrazide.

作者信息

Shahverdizadeh Gholam Hossein, Bikas Rahman, Eivazi Maryam, Mahboubi Anarjan Parisa, Notash Behrouz

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2011 Feb 26;67(Pt 3):o713. doi: 10.1107/S1600536811006088.

Abstract

In the title compound, C(18)H(16)N(2)O(3)S, the dihedral angle between the planes of the benzene ring and the naphthyl ring system is 83.37 (10)°. An intra-molecular O-H⋯N hydrogen bond occurs. Inter-molecular N-H⋯O hydrogen bonds stabilize the crystal structure. There is a π-π inter-action between the naphthyl ring systems [centroid-centroid distance = 3.7556 (15) Å]. In addition, naphth-yl-tolyl and naphth-yl-naphthyl C-H⋯π inter-actions are observed.

摘要

在标题化合物C(18)H(16)N(2)O(3)S中,苯环平面与萘环体系平面之间的二面角为83.37 (10)°。存在分子内O-H⋯N氢键。分子间N-H⋯O氢键使晶体结构得以稳定。萘环体系之间存在π-π相互作用[质心-质心距离 = 3.7556 (15) Å]。此外,还观察到萘基-甲苯基和萘基-萘基的C-H⋯π相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/13ff/3052163/a6a00394bc4b/e-67-0o713-fig1.jpg

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