Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093, China.
Chem Commun (Camb). 2012 Oct 21;48(82):10249-51. doi: 10.1039/c2cc35456j.
A series of Cu(II) complexes showed unprecedented reversible cascades of single-crystal-to-single-crystal (SCSC) transformations, and more interestingly, very rapid crystal dynamic processes were observed in this system via the substitution of coordinating components without loss of single crystallinity.
一系列的 Cu(II) 配合物表现出前所未有的单晶到单晶(SCSC)转变的级联可逆性,更有趣的是,通过取代配位组分,在不损失单晶的情况下,观察到该体系中非常快速的晶体动力学过程。