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基于联二萘酚的手性聚铵受体用于水溶液中(S,S)-酒石酸的高对映选择性识别和荧光传感。

A BINOL-based chiral polyammonium receptor for highly enantioselective recognition and fluorescence sensing of (S,S)-tartaric acid in aqueous solution.

机构信息

Dipartimento di Chimica Ugo Schiff, Università di Firenze, Via della Lastruccia 3, 50019-Sesto Fiorentino, Firenze, Italy.

出版信息

Chem Commun (Camb). 2012 Oct 28;48(84):10428-30. doi: 10.1039/c2cc35383k. Epub 2012 Sep 17.

DOI:10.1039/c2cc35383k
PMID:22983504
Abstract

A chiral ditopic polyammonium receptor featuring two [9]aneN(3) moieties separated by a (S)-BINOL linker is able to selectively bind and sense in water (S,S)-tartaric acid over its (R,R)/meso forms.

摘要

一种手性双齿聚铵受体,具有两个由 (S)-BINOL 连接体分隔的 [9]aneN(3) 部分,能够在水中选择性地结合和识别 (S,S)-酒石酸,而不是其 (R,R)/meso 形式。

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