Department of Chemistry, Carleton University, 1125 Colonel By Drive, Ottawa, K1S 5B6, Canada.
Chem Commun (Camb). 2012 Oct 28;48(84):10440-2. doi: 10.1039/c2cc35415b. Epub 2012 Sep 19.
A copper(I) iminopyrrolidinate was synthesized and evaluated by thermal gravimetric analysis (TGA), solution based (1)H NMR studies and surface chemistry to determine its thermal stability and decomposition mechanism. Copper(I) tert-butyl-imino-2,2-dimethylpyrrolidinate (1) demonstrated superior thermal stability and showed negligible decomposition in TGA experiments up to 300 °C as well as no decomposition in solutions at 165 °C over 3 weeks.
一种铜（I）亚氨基吡咯烷配合物通过热重分析（TGA）、溶液（1）H NMR 研究和表面化学进行了合成和评估，以确定其热稳定性和分解机制。铜（I）叔丁基亚氨基-2,2-二甲基吡咯烷（1）表现出优异的热稳定性，在 TGA 实验中高达 300°C 时几乎没有分解，在 165°C 的溶液中 3 周内也没有分解。
