Technische Universität Chemnitz, Faculty of Natural Sciences, Institute of Chemistry, Inorganic Chemistry, D-09107 Chemnitz, Germany.
Chem Commun (Camb). 2013 Aug 7;49(61):6855-7. doi: 10.1039/c3cc42914h. Epub 2013 Jun 21.
The synthesis of the novel copper(I) precursor [Cu(PPh3)2(O2CCH2OC2H4OC2H4OCH3)] and its application in the straightforward solution synthesis of oxide-free copper nanoparticles by mere thermal decomposition are reported; depending on the precursor concentration particles of sizes of 10 nm or 30 nm are obtained in narrow size distributions.
报告了新型铜(I)前体[Cu(PPh3)2(O2CCH2OC2H4OC2H4OCH3)]的合成及其在仅通过热分解直接溶液合成无氧化物铜纳米粒子中的应用;根据前体浓度,可以得到粒径为 10nm 或 30nm 的颗粒,且粒径分布较窄。