一种氢键支架支撑的合成血红素 Fe(III)-O2(-)加合物。
A hydrogen bond scaffold supported synthetic heme Fe(III)-O2(-) adduct.
机构信息
Department of Inorganic Chemistry, Indian Association for the Cultivation of Science, India.
出版信息
Chem Commun (Camb). 2012 Nov 4;48(85):10535-7. doi: 10.1039/c2cc35162e.
PMID:22992672
Abstract
A hydrogen bonded heme-Fe(III)-O(2)(-) adduct is stabilized and characterized using resonance Raman and EPR spectroscopy. The low O-O vibrations of this complex are quite different from those reported for other heme-Fe(III)-O(2)(-) adducts.
摘要
采用共振拉曼和电子顺磁共振波谱技术稳定并表征了氢键结合的血红素-Fe(III)-O(2)(-)加合物。该配合物的低 O-O 振动与其他报道的血红素-Fe(III)-O(2)(-)加合物的振动明显不同。
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