手性芳基-铜（III）亲电试剂：在催化对映选择性芳基化和多米诺反应中开辟的新机遇。
Chiral aryl-copper(III) electrophiles: new opportunities in catalytic enantioselective arylations and domino processes.
机构信息
Institut Charles Gerhardt, UMR 5253 CNRS-UM2-UM1 ENSCM, Laboratoire Architectures Moléculaires et Matériaux Nanostructurés (AM2N), Ecole Nationale Supérieure de Chimie de Montpellier, 8 Rue de l'Ecole Normale, 34296 Montpellier, France.
出版信息
Angew Chem Int Ed Engl. 2012 Oct 29;51(44):10934-5. doi: 10.1002/anie.201205805. Epub 2012 Sep 23.
PMID:23001994
Abstract
"Chiral aryl cation" equivalents: The combination of diaryliodonium salts and catalytic amounts of chiral copper complexes provides facile access to "chiral aryl cation" synthons. These reagents offer new possibilities for asymmetric arylation reactions that initiate further domino processes.
摘要
手性芳基阳离子”等价物：二芳基碘鎓盐与催化量的手性铜配合物相结合，为制备“手性芳基阳离子”合成子提供了简便的方法。这些试剂为不对称芳基化反应提供了新的可能性，这些反应可以引发进一步的多米诺反应。
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