在[1,2]-烷基迁移与其他事件（如双自由基重排、施密特重排和碳正离子重排）相结合的合成和生物合成反应之间的类比。
Analogies between synthetic and biosynthetic reactions in which [1,2]-alkyl shifts are combined with other events: dyotropic, Schmidt, and carbocation rearrangements.
机构信息
Department of Chemistry, Univeristy of California-Davis, 1 Shields Avenue, Davis, California 95616, USA.
出版信息
J Org Chem. 2012 Oct 19;77(20):8845-50. doi: 10.1021/jo301864h. Epub 2012 Sep 28.
PMID:23006240
Abstract
A survey of computational studies on the mechanisms of dyotropic, Schmidt, and related reactions is presented. Connections between synthetically applied versions of these processes and those predicted to occur during biosynthetic terpene-forming carbocation cascades are highlighted.
摘要
本文综述了关于双亲和施密特反应及相关反应机理的计算研究。重点介绍了这些过程的合成应用版本与预测的生物合成萜类形成碳正离子级联反应之间的联系。
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