Department of Chemistry, Ludwig-Maximilians-Universität München, Butenandtstraße 5-13, 81377 München, Germany. Tel: +49 (0)89 2180 77800;
Beilstein J Org Chem. 2012;8:1523-7. doi: 10.3762/bjoc.8.172. Epub 2012 Sep 12.
We report the elusive X-ray structure of the Dess-Martin periodinane (DMP), a hypervalent iodine reagent popular amongst synthetic chemists. In the solid state, the highly crystalline compound forms an intricate coordination polymer held together by intermolecular halogen and hydrogen bonds.
我们报道了难以捉摸的 Dess-Martin -periodinane（DMP）的 X 射线结构，DMP 是一种深受合成化学家欢迎的高价碘试剂。在固态下，这种高结晶化合物形成了一种复杂的配位聚合物，通过分子间的卤素和氢键结合在一起。
