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用于 DSC 应用的基于 DPP 的敏化剂的结构研究。

A structural study of DPP-based sensitizers for DSC applications.

机构信息

Laboratory for Photonics and Interfaces, Institution of Chemical Sciences and Engineering, School of Basic Sciences, Swiss Federal Institute of Technology, CH-1015 Lausanne, Switzerland.

出版信息

Chem Commun (Camb). 2012 Nov 11;48(87):10724-6. doi: 10.1039/c2cc35125k.

Abstract

Four D-π-A sensitizers comprising a thienyl-diketopyrrolopyrrole (ThDPP) bridge were synthesized and tested in iodide/triiodide liquid electrolyte DSC devices. The dye series was strategically designed to develop a structure-property relationship. The best performing sensitizer utilized a phenyl-based anchor and triphenylamine donor (η = 5.03%).

摘要

四种包含噻吩二酮吡咯并吡咯(ThDPP)桥的 D-π-A 敏化剂被合成并在碘/三碘液体电解质 DSC 器件中进行了测试。该染料系列是经过精心设计的,旨在建立结构-性能关系。表现最好的敏化剂采用了基于苯基的锚定和三苯胺供体(η=5.03%)。

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