Department of Chemical Engineering, University of Cordoba, Spain.
Bioresour Technol. 2012 Dec;125:249-55. doi: 10.1016/j.biortech.2012.08.108. Epub 2012 Sep 5.
Different cellulose pulps were produced from sulfur-free chemical treatments of Empty Palm Fruit Bunch Fibers (EPFBF), a by-product from palm oil processing. The pulps were microfluidized for deconstruction into nanofibrillated cellulose (NFC) and nanopaper was manufactured by using an overpressure device. The morphological and structural features of the obtained NFCs were characterized via atomic force and scanning electron microscopies. The physical properties as well as the interactions with water of sheets from three different pulps were compared with those of nanopaper obtained from the corresponding NFC. Distinctive chemical and morphological characteristics and ensuing nanopaper properties were generated by the EPFBF fibers. The NFC grades obtained compared favorably with associated materials typically produced from bleached wood fibers. Lower water absorption, higher tensile strengths (107-137 MPa) and elastic modulus (12-18 GPa) were measured, which opens the possibility for valorization of such widely available bioresource.
不同的纤维素浆粕是通过对棕榈油加工副产物空棕果串纤维(Empty Palm Fruit Bunch Fibers,EPFBF)进行无硫化学处理制备的。将浆粕进行微流化处理以解构成纳米原纤化纤维素(Nanofibrillated Cellulose,NFC),并使用超压装置制造纳米纸。通过原子力显微镜和扫描电子显微镜对获得的 NFC 的形态和结构特征进行了表征。比较了三种不同浆粕制成的纸张与相应 NFC 制成的纳米纸的物理性能以及与水的相互作用。EPFBF 纤维产生了独特的化学和形态特征以及后续的纳米纸性能。所获得的 NFC 等级与通常由漂白木纤维生产的相关材料相比具有优势。测量结果表明,纳米纸具有较低的吸水率、更高的拉伸强度(107-137 MPa)和弹性模量(12-18 GPa),这为这种广泛可用的生物质资源的增值利用开辟了可能性。