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将动力学受限模型驱动到非平衡稳态:结构和慢输运性质。

Driving kinetically constrained models into nonequilibrium steady states: Structural and slow transport properties.

作者信息

Turci Francesco, Pitard Estelle, Sellitto Mauro

机构信息

Laboratoire Charles Coulomb, Université Montpellier II and CNRS, 34095 Montpellier, France.

出版信息

Phys Rev E Stat Nonlin Soft Matter Phys. 2012 Sep;86(3 Pt 1):031112. doi: 10.1103/PhysRevE.86.031112. Epub 2012 Sep 10.

Abstract

Complex fluids in shear flow and biased dynamics in crowded environments exhibit counterintuitive features which are difficult to address both at a theoretical level and by molecular dynamic simulations. To understand some of these features we study a schematic model of a highly viscous liquid, the two-dimensional Kob-Andersen kinetically constrained model, driven into nonequilibrium steady states by a uniform non-Hamiltonian force. We present a detailed numerical analysis of the microscopic behavior of the model, including transversal and longitudinal spatial correlations and dynamic heterogeneities. In particular, we show that at high particle density the transition from positive to negative resistance regimes in the current vs field relation can be explained via the emergence of nontrivial structures that intermittently trap the particles and slow down the dynamics. We relate such spatial structures to the current vs field relation in the different transport regimes.

摘要

复杂流体在剪切流中以及拥挤环境中的有偏动力学表现出违反直觉的特征,这在理论层面和分子动力学模拟中都难以处理。为了理解其中一些特征,我们研究了一种高粘性液体的简化模型,即二维Kob-Andersen动力学受限模型,它由均匀的非哈密顿力驱动至非平衡稳态。我们对该模型的微观行为进行了详细的数值分析,包括横向和纵向空间相关性以及动态非均匀性。特别地,我们表明在高粒子密度下,电流与场关系中从正电阻区域到负电阻区域的转变可以通过间歇性捕获粒子并减缓动力学的非平凡结构的出现来解释。我们将这种空间结构与不同输运区域中的电流与场关系联系起来。

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