Knežević Miloš, Evans R M L
Cavendish Laboratory, University of Cambridge, Cambridge CB3 0HE, United Kingdom.
School of Mathematics, University of Leeds, LS2 9JT, United Kingdom.
Phys Rev E Stat Nonlin Soft Matter Phys. 2014 Jan;89(1):012132. doi: 10.1103/PhysRevE.89.012132. Epub 2014 Jan 22.
We investigate the correspondence between a nonequilibrium ensemble defined via the distribution of phase-space paths of a Hamiltonian system and a system driven into a steady state by nonequilibrium boundary conditions. To discover whether the nonequilibrium path ensemble adequately describes the physics of a driven system, we measure transition rates in a simple one-dimensional model of rotors with Newtonian dynamics and purely conservative interactions. We compare those rates with known properties of the nonequilibrium path ensemble. In doing so, we establish effective protocols for the analysis of transition rates in nonequilibrium quasisteady states. Transition rates between potential wells and also between phase-space elements are studied and found to exhibit distinct properties, the more coarse-grained potential wells being effectively further from equilibrium. In all cases the results from the boundary-driven system are close to the path-ensemble predictions, but the question of equivalence of the two remains open.
我们研究了通过哈密顿系统相空间路径分布定义的非平衡系综与由非平衡边界条件驱动至稳态的系统之间的对应关系。为了探究非平衡路径系综是否能充分描述受驱系统的物理特性,我们在一个具有牛顿动力学和纯保守相互作用的简单一维转子模型中测量跃迁速率。我们将这些速率与非平衡路径系综的已知特性进行比较。在此过程中,我们建立了用于分析非平衡准稳态跃迁速率的有效方案。研究了势阱之间以及相空间元素之间的跃迁速率,发现它们呈现出不同的特性,粒度越粗的势阱实际上离平衡态更远。在所有情况下,边界驱动系统的结果都与路径系综的预测相近,但两者的等效性问题仍未解决。