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用于碳纳米管增强聚合物复合材料的自动分散和取向分析。

Automated dispersion and orientation analysis for carbon nanotube reinforced polymer composites.

机构信息

Psychiatry Neuroimaging Laboratory, Harvard Medical School, Boston, MA 02115, USA.

出版信息

Nanotechnology. 2012 Nov 2;23(43):435706. doi: 10.1088/0957-4484/23/43/435706. Epub 2012 Oct 11.

Abstract

The properties of carbon nanotube (CNT)/polymer composites are strongly dependent on the dispersion and orientation of CNTs in the host matrix. Quantification of the dispersion and orientation of CNTs by means of microstructure observation and image analysis has been demonstrated as a useful way to understand the structure-property relationship of CNT/polymer composites. However, due to the various morphologies and large amount of CNTs in one image, automatic and accurate identification of CNTs has become the bottleneck for dispersion/orientation analysis. To solve this problem, shape identification is performed for each pixel in the filler identification step, so that individual CNTs can be extracted from images automatically. The improved filler identification enables more accurate analysis of CNT dispersion and orientation. The dispersion index and orientation index obtained for both synthetic and real images from model compounds correspond well with the observations. Moreover, these indices help to explain the electrical properties of CNT/silicone composite, which is used as a model compound. This method can also be extended to other polymer composites with high-aspect-ratio fillers.

摘要

碳纳米管(CNT)/聚合物复合材料的性能强烈依赖于 CNT 在基体中的分散和取向。通过微观结构观察和图像分析来定量 CNT 的分散和取向,已被证明是理解 CNT/聚合物复合材料结构-性能关系的一种有用方法。然而,由于一个图像中 CNT 的各种形态和数量庞大,因此自动且准确地识别 CNT 已成为分散/取向分析的瓶颈。为了解决这个问题,在填料识别步骤中对每个像素进行形状识别,从而可以自动从图像中提取单个 CNT。改进的填料识别使 CNT 分散和取向的分析更加准确。从模型化合物中获得的合成和真实图像的分散指数和取向指数与观察结果非常吻合。此外,这些指数有助于解释作为模型化合物的 CNT/硅橡胶复合材料的电性能。该方法还可以扩展到具有高纵横比填料的其他聚合物复合材料。

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Polymer Composite Containing Carbon Nanotubes and their Applications.含碳纳米管的聚合物复合材料及其应用
Recent Pat Nanotechnol. 2017 Jul 10;11(2):109-115. doi: 10.2174/1872210510666161027155916.

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