光导向动态球的合理设计。

Rational design of light-directed dynamic spheres.

机构信息

Department of Chemistry and Department of Electronic Chemistry, Tokyo Institute of Technology, Yokohama 226-8502, Japan.

出版信息

Chem Commun (Camb). 2012 Dec 14;48(96):11763-5. doi: 10.1039/c2cc36443c. Epub 2012 Oct 31.

DOI:10.1039/c2cc36443c

PMID:23114501

Abstract

We created light-directed dynamic spheres based on simple azobenzene monomers showing (i) a high yield of reversible trans↔cis photoisomerization and (ii) noticeable phase transition from crystalline to isotropic states under UV light irradiation at ambient temperature.

摘要

我们基于简单的偶氮苯单体创建了光导向动态球体，其具有以下特点：（i）高比例的可逆反式-顺式光异构化，以及（ii）在环境温度下通过紫外线照射从结晶态到各向同性态的显著相变。