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（1-{（E）-[苯基（吡啶-2-基-κN）亚甲基]氨基-κN}吡咯烷-2-酮-κO）双（硫氰酸根合-κN）铜（II）

(1-{(E)-[Phen-yl(pyridin-2-yl-κN)methyl-idene]amino-κN}pyrrolidin-2-one-κO)bis-(thio-cyanato-κN)copper(II).

作者信息

Kunnath Roji J, Prathapachandra Kurup M R, Ng Seik Weng

机构信息

Department of Applied Chemistry, Cochin University of Science and Technology, Kochi 682 022, India.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Oct 1;68(Pt 10):m1302. doi: 10.1107/S1600536812039918. Epub 2012 Sep 26.

DOI:10.1107/S1600536812039918
PMID:23125616
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3470172/
Abstract

The Cu(II) atom in the title compound, [Cu(NCS)(2)(C(16)H(15)N(3)O)], is bonded to the N atoms of two thio-cyanate ions, and is N,N'-chelated by the Schiff base ligand. The four N atoms surround the metal atom to form a distorted square; the square environment is distorted towards a square pyramid by a long Cu⋯O inter-action. In the crystal, two C atoms of the pyrrolidin-2-one ring are disordered over two positions in a 1:1 ratio.

摘要

在标题化合物[Cu(NCS)₂(C₁₆H₁₅N₃O)]中，铜（II）原子与两个硫氰酸根离子的氮原子键合，并被席夫碱配体进行N,N'-螯合。四个氮原子围绕金属原子形成一个扭曲的正方形；通过一个长的Cu⋯O相互作用，正方形环境向四方锥扭曲。在晶体中，吡咯烷-2-酮环的两个碳原子在两个位置上以1:1的比例无序排列。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/37ce/3470172/c8f3ccb3000d/e-68-m1302-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/37ce/3470172/c8f3ccb3000d/e-68-m1302-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/37ce/3470172/c8f3ccb3000d/e-68-m1302-fig1.jpg

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本文引用的文献

1
Dichlorido(1-{(E)-[phen-yl(pyridin-2-yl-κN)methyl-idene]amino-κN}pyrrolidin-2-one-κO)copper(II) monohydrate.
Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):m1181. doi: 10.1107/S1600536812035398. Epub 2012 Aug 23.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.