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Dichlorido(1-{(E)-[phen-yl(pyridin-2-yl-κN)methyl-idene]amino-κN}pyrrolidin-2-one-κO)copper(II) monohydrate.

作者信息

Kunnath Roji J, Prathapachandra Kurup M R, Ng Seik Weng

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):m1181. doi: 10.1107/S1600536812035398. Epub 2012 Aug 23.

DOI:10.1107/S1600536812035398
PMID:22969476
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3435603/
Abstract

The Cu(II) atom in the title compound, [CuCl(2)(C(16)H(15)N(3)O)]·H(2)O, is N,N',O-chelated by the neutral Schiff base ligand and exists in a square-pyramidal geometry. It is displaced by 0.316 (1) Å out of the square plane (r.m.s. deviation = 0.015 Å) in the direction of the apical Cl atom. The apical Cl atoms of adjacent complex units are hydrogen-bond acceptors to two water mol-ecules, the inter-action generating a centrosymmetric dimer through a cyclic R(4) (2)(8) association.

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8265/3435603/9b63e0dffbeb/e-68-m1181-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8265/3435603/082ae3e6c718/e-68-m1181-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8265/3435603/9b63e0dffbeb/e-68-m1181-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8265/3435603/082ae3e6c718/e-68-m1181-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8265/3435603/9b63e0dffbeb/e-68-m1181-fig2.jpg

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引用本文的文献

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2
(1-{(E)-[Phen-yl(pyridin-2-yl-κN)methyl-idene]amino-κN}pyrrolidin-2-one-κO)bis-(thio-cyanato-κN)copper(II).（1-{（E）-[苯基（吡啶-2-基-κN）亚甲基]氨基-κN}吡咯烷-2-酮-κO）双（硫氰酸根合-κN）铜（II）
Acta Crystallogr Sect E Struct Rep Online. 2012 Oct 1;68(Pt 10):m1302. doi: 10.1107/S1600536812039918. Epub 2012 Sep 26.

本文引用的文献

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Graph-set analysis of hydrogen-bond patterns in organic crystals.有机晶体中氢键模式的图形集分析。
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