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(Cyanato-κN){1-[(E)-phen-yl(pyridin-2-yl-κN)methyl-idene]semicarbazidato-κ(2)N(1),O}copper(II).

作者信息

Kunnath Roji J, Prathapachandra Kurup M R, Ng Seik Weng

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Sep 1;68(Pt 9):m1180. doi: 10.1107/S1600536812035386. Epub 2012 Aug 23.

DOI:10.1107/S1600536812035386
PMID:22969475
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3435602/
Abstract

The Cu(II) atom in the title compound, [Cu(C(13)H(11)N(4)O)(NCO)], is N,N',O-chelated by the mono-deprotonated Schiff base ligand and it is also covalently bonded to the nitro-gen end of the cyanate ion. The Cu(II) atom shows a square-planar coordination that is distorted towards square-pyramidal owing to an inter-molecular Cu⋯N(cyanate) inter-action [2.623 (2) Å], which gives a centrosymmetric dimer. In the square-planar description, the Cu(II) atom is displaced out of the square plane [r.m.s. deviation = 0.048 Å] by 0.084 (1) Å in the direction of the apical occupant. In the crystal, adjacent complex dimers are linked by an amine N-H⋯N hydrogen-bond pair, also giving a centrosymmetric cyclic association [graph set R(2) (2)(8)], generating a linear chain parallel to [110].

摘要
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f827/3435602/bfdbe75fc191/e-68-m1180-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f827/3435602/bfdbe75fc191/e-68-m1180-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/f827/3435602/bfdbe75fc191/e-68-m1180-fig1.jpg

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本文引用的文献

1
2-Benzoyl-pyridine semicarbazone.2-苯甲酰基吡啶缩氨基脲
Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 6;64(Pt 1):o177. doi: 10.1107/S1600536807064628.
2
A short history of SHELX.SHELX简史。
Acta Crystallogr A. 2008 Jan;64(Pt 1):112-22. doi: 10.1107/S0108767307043930. Epub 2007 Dec 21.
3
Graph-set analysis of hydrogen-bond patterns in organic crystals.有机晶体中氢键模式的图形集分析。
Acta Crystallogr B. 1990 Apr 1;46 ( Pt 2):256-62. doi: 10.1107/s0108768189012929.