过氧自由基和 DPPH·自由基与氢键酚反应中的质子-电子转移途径。
Proton-electron transfer pathways in the reactions of peroxyl and dpph˙ radicals with hydrogen-bonded phenols.
机构信息
Department of Chemistry Ciamician, University of Bologna, Via San Giacomo 11, 40126, Bologna, Italy.
出版信息
Chem Commun (Camb). 2012 Dec 18;48(97):11904-6. doi: 10.1039/c2cc36531f.
PMID:23125978
Abstract
The kinetics of the reaction of peroxyl and dpph˙ radicals with phenols H-bonded to N-bases have been studied for the first time. Electron-transfer processes are observed in MeCN but only with the dpph˙ radical.
摘要
首次研究了与 N-碱氢键合的酚与过氧自由基和 DPPH·自由基的反应动力学。在 MeCN 中观察到电子转移过程，但仅与 DPPH·自由基有关。
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