γ-选择性导向催化不对称烯丙基硼氢化反应。
γ-Selective directed catalytic asymmetric hydroboration of 1,1-disubstituted alkenes.
机构信息
Department of Chemistry, University of Nebraska-Lincoln, Lincoln, Nebraska, USA.
出版信息
Chem Commun (Camb). 2012 Dec 28;48(100):12180-2. doi: 10.1039/c2cc36199j.
Abstract
Directed catalytic asymmetric hydroborations of 1,1-disubstituted alkenes afford γ-dioxaborato amides and esters in high enantiomeric purity (90-95% ee).
摘要
导向催化不对称氢硼化反应可使 1,1-取代烯烃高对映选择性地生成γ-二氧硼酰胺和酯（90-95%ee）。
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