Institut Charles Gerhardt de Montpellier, ICGM-MACS, UMR 5253 CNRS-ENSCM-UM2-UM1, 8 rue de l'Ecole Normale, 34296 Montpellier cedex 5, France.
Chem Soc Rev. 2013 May 7;42(9):3808-20. doi: 10.1039/c2cs35368g. Epub 2012 Nov 20.
In this tutorial review we intend to give an overview of the potential of NMR spectroscopy, and in particular solid-state NMR, in characterising micelle-templated mesoporous materials. Different topics are covered including the study of formation mechanisms, the characterisation of structures, textures, surfaces and interfaces, functionalisation, dynamic properties and structure-reactivity correlations. Some selected examples illustrate the variety of information provided by this spectroscopy. Particular attention is paid to recent technological and/or methodological developments.
在本教程综述中,我们旨在概述 NMR 光谱学,特别是固态 NMR 在表征胶束模板介孔材料方面的潜力。涵盖了不同的主题,包括形成机制的研究、结构、织构、表面和界面的表征、功能化、动态性质和结构-反应性关系。一些选定的例子说明了该光谱学提供的各种信息。特别关注了最近的技术和/或方法学发展。