Key Laboratory of Cluster Science of Ministry of Education, School of Chemistry, Beijing Institution of Technology, 5 South Zhongguancun Street, Haidian District, Beijing, 100081, PR China.
Dalton Trans. 2013 Feb 7;42(5):1342-5. doi: 10.1039/c2dt31896b. Epub 2012 Nov 21.
We report a catalytic eight-cobalt-capped α-Keggin polyoxoazocobaltite with a highly symmetric structure completely constructed from the late transition-metal Co(II) as a poly atom, Co(20)(OH)(24)(MMT)(12)(SO(4))(2)·6H(2)O (1) (MMT: 2-mercapto-5-methyl-1,3,4-thiadiazole). To the best of our knowledge, this is the first homometallic Co(II) magnetic cluster bearing Keggin structure. It can serve as a potential catalyst in the styrene polymerization.
我们报告了一种催化的八钴封端的α-Keggin 聚氧杂钴酸盐，其具有完全由后过渡金属 Co(II) 作为多原子构建的高度对称结构，Co(20)(OH)(24)(MMT)(12)(SO(4))(2)·6H(2)O (1)（MMT：2-巯基-5-甲基-1,3,4-噻二唑）。据我们所知，这是第一个具有 Keggin 结构的同核 Co(II) 磁性簇。它可以用作苯乙烯聚合中的潜在催化剂。
