Instituto Síntesis Química y Catálisis Homogénea, Departamento de Química Inórganica, CSIC-Universidad de Zaragoza, Facultad de Ciencias, Spain.
Angew Chem Int Ed Engl. 2013 Jan 2;52(1):211-22. doi: 10.1002/anie.201205468. Epub 2012 Dec 4.
The hydrothiolation of unsaturated carbon-carbon bonds is a practical and atom-economical approach for the incorporation of sulfur into organic frameworks. In recent years, we have witnessed the development of a range of transition-metal-based catalytic systems for the control of the regio- and stereoselectivity. In this Minireview we highlight the mechanistic background behind this transformation so as to help the design of more specific and active organometallic hydrothiolation catalysts.
硫氢官能团化不饱和碳-碳键是一种将硫原子引入有机骨架的实用且原子经济性方法。近年来，我们见证了一系列基于过渡金属的催化体系的发展，这些体系可控制区域和立体选择性。在这篇综述中，我们强调了这种转化背后的机理背景，以帮助设计更具特异性和活性的有机金属硫氢官能团化催化剂。
