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[东湖表层水中全氟辛酸和全氟磺酸的空间分布]

[Spatial distribution of perfluorooctanoic acids and perfluorinate sulphonates in surface water of East Lake].

作者信息

Chen Jing, Wang Lin-ling, Zhu Hu-di, Wang Bei-bei, Liu Huang-cheng, Cao Meng-hua, Miao Zhu, Hu Li, Lu Xiao-hua, Liu Guang-hong

机构信息

research Institution of Environmental Science, Department of Environmental Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China.

出版信息

Huan Jing Ke Xue. 2012 Aug;33(8):2586-91.

Abstract

Concentrations and spatial distribution of PFOS and PFOA in surface water from East Lake in Wuhan, Hubei, China were studied. The total concentration of PFCs ranged from 31.1 to 237 ng x L(-1), and the mean value was 115 ng x L(-1), revealing lake-wide contamination in East Lake. PFOS and PFOA were detected in all samples with maximum values of 132 ng x L(-1) and 158 ng x L(-1), respectively, whereas the mean values of PFOS and PFOA were 60.4 and 55.0 ng x L(-1), respectively. The highest concentrations of PFOS and PFOA were found in the eastern area of lake, followed by the southern area of lake, and the western and northern areas of East Lake were the least contaminated regions. The specific distribution and composition profile of PFOS and PFOA, and the lack of significant correlation between PFOS and PFOA, suggested that there were various sources of PFCs. The PFOS concentrations at 30 sample sites (63%) were greater than 43 ng x L(-1), which was used to estimate an avian wildlife value for PFOS. The PFOA concentrations at 20 sample sites (42%) were greater than 40 ng x L(-1), which was a health-based guidance level recommended by the State of New Jersey for PFOA.

摘要

对中国湖北武汉东湖地表水全氟辛烷磺酸(PFOS)和全氟辛酸(PFOA)的浓度及空间分布进行了研究。全氟化合物(PFCs)的总浓度范围为31.1至237 ng·L⁻¹,平均值为115 ng·L⁻¹,表明东湖存在全湖范围的污染。所有样品中均检测到PFOS和PFOA,其最大值分别为132 ng·L⁻¹和158 ng·L⁻¹,而PFOS和PFOA的平均值分别为60.4和55.0 ng·L⁻¹。PFOS和PFOA的最高浓度出现在湖泊东部区域,其次是南部区域,东湖的西部和北部区域污染程度最低。PFOS和PFOA的具体分布和组成特征,以及PFOS和PFOA之间缺乏显著相关性,表明全氟化合物存在多种来源。30个采样点(63%)的PFOS浓度大于43 ng·L⁻¹,该浓度用于估算PFOS对鸟类野生动物的影响值。20个采样点(42%)的PFOA浓度大于40 ng·L⁻¹,这是新泽西州推荐的基于健康的PFOA指导水平。

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