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使用纳米氧化锌和多元羧酸处理棉织物的阻燃和抗紫外线性能。

Flame retardancy and UV protection of cotton based fabrics using nano ZnO and polycarboxylic acids.

机构信息

National Research Centre, Textile Division, Textile Chemistry and Technology, Department of Preparation and Finishing of Cellulosic Fibers, Tahrir St., Dokki, Cairo, PO Box 12311, Giza, Egypt.

出版信息

Carbohydr Polym. 2013 Jan 30;92(1):400-6. doi: 10.1016/j.carbpol.2012.08.085. Epub 2012 Aug 30.

Abstract

This research mainly deals with a novel flame-retardant and UV-protection for cellulosic fabrics using ZnO nanoparticles. We present the preparation and application of ZnO nanoparticles. The size of the prepared nanoparticles was analysed using dynamic light scattering (DLS). The application of nano ZnO on cellulosic fabrics (cotton 100% and cotton/cotton polyester 65/35%) was achieved by using different polycarboxilic acids (succinic acid [SA] and 1,2,3,4-butane tetracarboxilic acids [BTCA]) with sodium hypophosphite (SHP) as catalyst through conventional pad-dry-cure method. The effect of concentration of SHP on the physical properties, flammability and UV-protection of cross-linked fabrics are investigated. The effect of concentration of zinc oxide nanoparticles and the effect of curing temperature were also investigated. The results revealed the importance of SHP in increasing the flame-redundancy of the treated cellulosic fabrics.

摘要

这项研究主要涉及使用氧化锌纳米粒子为纤维素织物提供一种新型的阻燃和抗紫外线功能。我们介绍了氧化锌纳米粒子的制备和应用。使用动态光散射(DLS)分析了所制备的纳米粒子的尺寸。通过使用不同的聚羧酸(琥珀酸[SA]和 1,2,3,4-丁烷四羧酸[BTCA])和次亚磷酸钠(SHP)作为催化剂,通过常规的轧-烘-焙工艺,将纳米 ZnO 应用于纤维素织物(纯棉 100%和棉/涤 65/35%)上。研究了 SHP 的浓度对交联织物的物理性能、阻燃性和抗紫外线性能的影响。还研究了氧化锌纳米粒子的浓度和固化温度的影响。结果表明,SHP 在提高处理后的纤维素织物的阻燃性方面非常重要。

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