量子点纳米级异质结构用于太阳能转换。

Quantum dot nanoscale heterostructures for solar energy conversion.

机构信息

Department of Chemistry, University of Wisconsin-Madison, 1101 University Avenue, Madison, Wisconsin 53706, USA.

出版信息

Chem Soc Rev. 2013 Apr 7;42(7):2963-85. doi: 10.1039/c2cs35374a.

Abstract

Quantum dot nanoscale semiconductor heterostructures (QDHs) are a class of materials potentially useful for integration into solar energy conversion devices. However, realizing the potential of these heterostructured systems requires the ability to identify and synthesize heterostructures with suitably designed materials, controlled size and morphology of each component, and structural control over their shared interface. In this review, we will present the case for the utility and advantages of chemically synthesized QDHs for solar energy conversion, beginning with an overview of various methods of heterostructured material synthesis and a survey of heretofore reported materials systems. The fundamental charge transfer properties of the resulting materials combinations and their basic design principles will be outlined. Finally, we will discuss representative solar photovoltaic and photoelectrochemical devices employing QDHs (including quantum dot sensitized solar cells, or QDSSCs) and examine how QDH synthesis and design impacts their performance.

摘要

量子点纳米半导体异质结构（QDHs）是一类在太阳能转换器件集成中具有潜在应用价值的材料。然而，要实现这些异质结构系统的潜力，需要能够识别和合成具有合适设计材料、每个组件的受控尺寸和形态以及对其共享界面进行结构控制的异质结构。在本综述中，我们将提出化学合成 QDHs 在太阳能转换中的实用性和优势，首先概述各种异质结构材料合成方法，并调查迄今为止报道的材料系统。将概述所得材料组合的基本电荷转移特性及其基本设计原则。最后，我们将讨论采用 QDHs（包括量子点敏化太阳能电池或 QDSSCs）的代表性太阳能光伏和光电化学器件，并研究 QDH 合成和设计如何影响其性能。