反式二氯双（4-硝基苯胺-κN(1)）钯（II）
trans-Dichloridobis(4-nitro-aniline-κN(1))palladium(II).
作者信息
Feng Tian-Jun
机构信息
College of Mathematics, Physics and Software Engineering, Lanzhou Jiaotong University, Lanzhou 730070, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Nov 1;68(Pt 11):m1351. doi: 10.1107/S1600536812042134. Epub 2012 Oct 13.
In the title compound, [PdCl(2)(C(6)H(6)N(2)O(2))(2)], the Pd(II) atom is coordinated in a distorted square-planar geometry by two N atoms from two 4-nitro-aniline ligands and two Cl atoms in a trans arrangement. Inter-molecular N-H⋯Cl hydrogen bonds involving the amino groups and chloride anions lead to a chain along [100]. These chains are further self-assembled into a three-dimensional network through N-H⋯O and N-H⋯Cl hydrogen bonds.
在标题化合物[PdCl₂(C₆H₆N₂O₂)₂]中，Pd(II)原子由来自两个4-硝基苯胺配体的两个N原子和两个呈反式排列的Cl原子以扭曲的平面正方形几何构型配位。涉及氨基和氯离子阴离子的分子间N-H⋯Cl氢键导致沿着[100]方向形成一条链。这些链通过N-H⋯O和N-H⋯Cl氢键进一步自组装成三维网络。
Zotero 插件