Bon Volodimir, Orysyk Svitlana, Pekhnyo Vasyl
Institute of General and Inorganic Chemistry, NAS Ukraine, Kyiv, prosp. Palladina 32/34, 03680 Ukraine.
Acta Crystallogr Sect E Struct Rep Online. 2009 May 23;65(Pt 6):m673. doi: 10.1107/S1600536809018509.
In the title compound, [PdCl(2)(C(7)H(9)NO)(2)], the Pd atom is situated on a crystallographic centre of inversion. The coordination environment of the Pd atom shows a slightly distorted square-planar geometry. The crystal structure exhibits weak inter-molecular Pd⋯Cl inter-actions, with Pd⋯Cl distances of 3.6912 (6) Å. A chain-like arrangement of mol-ecules realized by inter-molecular N-H⋯Cl hydrogen bonds is observed along [010].
在标题化合物[PdCl₂(C₇H₉NO)₂]中,钯原子位于一个晶体学反演中心上。钯原子的配位环境呈现出略微扭曲的平面正方形几何构型。晶体结构中存在弱的分子间钯⋯氯相互作用,钯⋯氯距离为3.6912 (6) Å。沿着[010]方向观察到由分子间N - H⋯Cl氢键实现的分子链状排列。