Departamento de Química Inorgánica, Universidad de Granada, Avenida Fuentenueva s/n, 18071 Granada, Spain.
Inorg Chem. 2013 Jan 18;52(2):546-8. doi: 10.1021/ic302318j. Epub 2013 Jan 3.
We report the synthesis of a novel ligand, 3,3'-(1,2,4,5-tetrazine-3,6-diyl)dibenzoic acid (1). In this fragment, we have introduced two carboxylate groups with the aim of using this ligand as a linker to construct three-dimensional metal-organic frameworks (MOFs). We have been successful in the formation of zinc (2) and lanthanum (3) MOFs. The zinc compound is a two-dimensional structure, while the lanthanum material is a three-dimensional MOF with interesting channels. We include the luminescence and adsorption studies of these materials. Moreover, we have evaluated the in vitro toxicity of this novel ligand, concluding that it can be considered negligible.
我们报告了一种新型配体 3,3'-(1,2,4,5-四嗪-3,6-二基)二苯甲酸（1）的合成。在这个片段中，我们引入了两个羧酸盐基团，目的是使用该配体作为连接物来构建三维金属有机骨架（MOFs）。我们成功地合成了锌（2）和镧（3）MOFs。锌化合物是二维结构，而镧材料是具有有趣通道的三维 MOF。我们包括这些材料的发光和吸附研究。此外，我们还评估了这种新型配体的体外毒性，得出结论认为它可以忽略不计。
