Institute of Chemical Research of Catalonia (ICIQ), Av. Països Catalans 16, 43007 Tarragona, Spain.
J Am Chem Soc. 2013 Jan 30;135(4):1228-31. doi: 10.1021/ja311053h. Epub 2013 Jan 14.
An aluminum complex based on an amino triphenolate ligand scaffold shows unprecedented high activity (initial TOFs up to 36,000 h(-1)), broad substrate scope, and functional group tolerance in the formation of highly functional organic carbonates prepared from epoxides and CO(2). The developed catalytic protocol is further characterized by low catalyst loadings and relative mild reaction conditions using a cheap, abundant, and nontoxic metal.
一种基于三苯氨配体骨架的铝配合物在形成高功能性碳酸酯的反应中表现出前所未有的高活性（初始 TOF 高达 36000 h-1）、广泛的底物范围和官能团耐受性，这些碳酸酯是由环氧化物和 CO2 制备得到的。所开发的催化体系具有催化剂负载量低和相对温和的反应条件的特点，使用的是廉价、丰富和无毒的金属。
