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利用二氧化碳作为C1源合成六元环状碳酸酯(1,3-二氧杂环己烷-2-酮)的研究进展。

Advancements in six-membered cyclic carbonate (1,3-dioxan-2-one) synthesis utilizing carbon dioxide as a C1 source.

作者信息

Hosseinian Akram, Farshbaf Sepideh, Mohammadi Robab, Monfared Aazam, Vessally Esmail

机构信息

Department of Engineering Science, College of Engineering, University of Tehran P. O. Box 11365-4563 Tehran Iran.

Department of Chemistry, Center for Photochemical Sciences, Bowling Green State University Bowling Green Ohio 43403 USA.

出版信息

RSC Adv. 2018 May 16;8(32):17976-17988. doi: 10.1039/c8ra01280f. eCollection 2018 May 14.

Abstract

This review article surveys literature methods for the synthesis of six-membered cyclic carbonates using various substrates in the presence of CO with special emphasis on the mechanistic aspects of the reactions. We have classified these reactions based on the type of starting material.

摘要

这篇综述文章概述了在一氧化碳存在下使用各种底物合成六元环状碳酸酯的文献方法,特别强调了反应的机理方面。我们根据起始原料的类型对这些反应进行了分类。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/df5a/9080536/3bd2632e7e69/c8ra01280f-f1.jpg

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