客体诱导的水溶性大笼 Cavitand 组装状态的转换。
Guest-mediated switching of the assembly state of a water-soluble deep-cavity cavitand.
机构信息
Department of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556-5670, USA.
出版信息
Chem Commun (Camb). 2013 Feb 18;49(14):1395-7. doi: 10.1039/c2cc38227j.
PMID:23306216
Abstract
Deep-cavity cavitand TEMOA (2) is shown to assemble via the hydrophobic effect into tetrameric and hexameric assemblies. With inner volumes of 1400-1500 Å(3) and 3200-3700 Å(3) respectively, these well-defined and mono-dispersed assemblies represent the largest of their type to date.
摘要
深腔穴状分子 TEMOA（2）通过疏水作用自组装形成四聚体和六聚体。这些具有明确的单分散性的组装体的内腔体积分别为 1400-1500 Å(3)和 3200-3700 Å(3)，是迄今为止同类中最大的。
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