醛的可见光光氧化还原催化 C-C 键断裂。
Oxidative C-C bond cleavage of aldehydes via visible-light photoredox catalysis.
机构信息
State Key Lab of Urban Water Resource and Environment, the Academy of Fundamental and Interdisciplinary Sciences, Harbin Institute of Technology, Harbin 150080, China.
出版信息
Org Lett. 2013 Feb 1;15(3):624-7. doi: 10.1021/ol303437m. Epub 2013 Jan 11.
PMID:23311894
Abstract
The visible-light mediated oxidative C-C bond cleavage of aldehydes has been achieved in good yields at ambient temperature and open to air using Ru(bpy)(3)Cl(2) (bpy = 2,2'-bipyridine) as the photoredox catalyst. Moreover, we further demonstrated the application in a tandem Michael/oxidative C-C bond cleavage reaction.
摘要
可见光促进的醛的 C-C 键氧化断裂在环境温度和开放空气条件下以良好的收率实现，使用 Ru(bpy)(3)Cl(2)（bpy = 2,2'-联吡啶）作为光氧化还原催化剂。此外，我们进一步证明了其在串联迈克尔/氧化 C-C 键断裂反应中的应用。
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