State Key Lab of Urban Water Resource and Environment, the Academy of Fundamental and Interdisciplinary Sciences, Harbin Institute of Technology, Harbin 150080, China.
Org Lett. 2013 Feb 1;15(3):624-7. doi: 10.1021/ol303437m. Epub 2013 Jan 11.
The visible-light mediated oxidative C-C bond cleavage of aldehydes has been achieved in good yields at ambient temperature and open to air using Ru(bpy)(3)Cl(2) (bpy = 2,2'-bipyridine) as the photoredox catalyst. Moreover, we further demonstrated the application in a tandem Michael/oxidative C-C bond cleavage reaction.
可见光促进的醛的 C-C 键氧化断裂在环境温度和开放空气条件下以良好的收率实现，使用 Ru(bpy)(3)Cl(2)（bpy = 2,2'-联吡啶）作为光氧化还原催化剂。此外，我们进一步证明了其在串联迈克尔/氧化 C-C 键断裂反应中的应用。
Zotero 插件