Departamento de Física-ICE, Universidade Federal do Amazonas, Manaus-AM, Brazil.
J Magn Reson. 2013 Feb;227:87-92. doi: 10.1016/j.jmr.2012.12.004. Epub 2012 Dec 20.
The ESR of a magnetic probe sited at a distance R from an adatom in graphene, interacting via a RKKY interaction, is studied. The spin relaxation rate of the magnetic probe in the case of pristine graphene satisfies a T(3) dependence for all temperatures at the Dirac point. However, away from the Dirac point a T(3) dependence is observed only for high temperatures unlike the Korringa behavior at low temperatures. Moreover, the zero-temperature relaxation rate of the pristine graphene demonstrates a quadratic dependence on the chemical potential. In the presence of the magnetic adatom hybridized with one site of the graphene sublattice we observe a dip in the relaxation rate away from the Dirac point. At the Dirac point a deviation from the T(3) dependence is observed. The presence of the Coulomb interaction U also modifies the zero-temperature relaxation rate when compared to that of pristine graphene. The transition from the magnetic state to the non-magnetic state is also characterized by a minimum in the relaxation rate.
研究了位于石墨烯近邻原子位置距离为 R 的磁探针的 ESR,该磁探针通过 RKKY 相互作用相互作用。在狄拉克点处,对于原始石墨烯,磁探针的自旋弛豫率在所有温度下都满足 T(3)依赖性。然而,与低温下的科灵格行为不同,在狄拉克点之外仅在高温下观察到 T(3)依赖性。此外,原始石墨烯的零温弛豫率表现出对化学势的二次依赖关系。在与石墨烯子晶格的一个位点杂化的磁性近邻原子存在的情况下,我们观察到远离狄拉克点的弛豫率出现下降。在狄拉克点处,观察到与 T(3)依赖性的偏离。与原始石墨烯相比,库仑相互作用 U 的存在也会改变零温弛豫率。从磁性状态到非磁性状态的转变也由弛豫率的最小值来表征。