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具有量子点/N 掺杂 CNT 杂化纳米材料的有机太阳能电池中的激子解离和电荷输运增强。

Exciton dissociation and charge-transport enhancement in organic solar cells with quantum-dot/N-doped CNT hybrid nanomaterials.

机构信息

Center for Nanomaterials and Chemical Reactions, Institute for Basic Science (IBS), Department of Materials Science and Engineering, KAIST, Daejeon, Republic of Korea.

出版信息

Adv Mater. 2013 Apr 11;25(14):2011-7. doi: 10.1002/adma.201204454. Epub 2013 Jan 14.

Abstract

The incorporation of InP quantum-dot/N-doped multiwalled carbon nanotube (QD:NCNT) nanohybrids in the active layer of poly(3-hexylthiophene)/indene-C60 bisadduct (P3HT/ICBA) bulk-heterojuction solar cells enhances V(OC) and J(SC) . The QDs encourage exciton dissociation by promoting electron transfer, while the NCNTs enhance the transport of the separated electrons and eventual charge collection. Such a synergistic effect successfully improves the power conversion efficiency (PCE) from 4.68% (reference cells) to 6.11%.

摘要

将 InP 量子点/N 掺杂多壁碳纳米管(QD:NCNT)纳米杂化物掺入聚(3-己基噻吩)/茚并[2,1-b]噻吩-C60 双加成物(P3HT/ICBA)体异质结太阳能电池的活性层中,可提高开路电压(VOC)和短路电流密度(JSC)。量子点通过促进电子转移来促进激子解离,而 NCNTs 则增强了分离电子的传输以及最终的电荷收集。这种协同效应成功地将功率转换效率(PCE)从 4.68%(基准电池)提高到了 6.11%。

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