• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

A cationic high-valent Cp*Co(III) complex for the catalytic generation of nucleophilic organometallic species: directed C-H bond activation.

作者信息

Yoshino Tatsuhiko, Ikemoto Hideya, Matsunaga Shigeki, Kanai Motomu

机构信息

Graduate School of Pharmaceutical Sciences, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.

出版信息

Angew Chem Int Ed Engl. 2013 Feb 18;52(8):2207-11. doi: 10.1002/anie.201209226. Epub 2013 Jan 16.

DOI:10.1002/anie.201209226
PMID:23325538
Abstract
摘要

相似文献

1
A cationic high-valent Cp*Co(III) complex for the catalytic generation of nucleophilic organometallic species: directed C-H bond activation.用于催化生成亲核有机金属物种的阳离子高价环戊二烯基钴（III）配合物：导向C-H键活化
Angew Chem Int Ed Engl. 2013 Feb 18;52(8):2207-11. doi: 10.1002/anie.201209226. Epub 2013 Jan 16.
2
Cobalt-catalyzed, room-temperature addition of aromatic imines to alkynes via directed C-H bond activation.钴催化、室温条件下通过导向 C-H 键活化实现芳基亚胺与炔烃的加成反应。
J Am Chem Soc. 2011 Nov 2;133(43):17283-95. doi: 10.1021/ja2047073. Epub 2011 Oct 11.
3
Synthesis of Fluorine-Containing 6-Arylpurine Derivatives via Cp*Co(III)-Catalyzed C-H Bond Activation.通过Cp*Co(III)催化的C-H键活化合成含氟6-芳基嘌呤衍生物
Chem Pharm Bull (Tokyo). 2018;66(1):51-54. doi: 10.1248/cpb.c17-00797.
4
A Cp*CoI2-dimer as a precursor for cationic Co(III)-catalysis: application to C-H phosphoramidation of indoles.一种作为阳离子钴（III）催化前体的茂基钴（II）二聚体：在吲哚的C-H磷酰胺化反应中的应用。
Chem Commun (Camb). 2015 Mar 18;51(22):4659-61. doi: 10.1039/c4cc10284c.
5
Cp*Co(III) Catalyzed Site-Selective C-H Activation of Unsymmetrical O-Acyl Oximes: Synthesis of Multisubstituted Isoquinolines from Terminal and Internal Alkynes.Cp*Co(III) 催化的不对称 O-酰基肟的位点选择性 C-H 活化：末端和内部炔烃合成多取代异喹啉。
Angew Chem Int Ed Engl. 2015 Oct 26;54(44):12968-72. doi: 10.1002/anie.201507744. Epub 2015 Sep 28.
6
Pyrroloindolone synthesis via a Cp*Co(III)-catalyzed redox-neutral directed C-H alkenylation/annulation sequence.通过 Cp*Co(III)-催化的氧化还原中性导向 C-H 烯基化/环化序列合成吡咯并吲哚酮。
J Am Chem Soc. 2014 Apr 9;136(14):5424-31. doi: 10.1021/ja5008432. Epub 2014 Mar 31.
7
Cobalt-catalyzed hydroarylation of alkynes through chelation-assisted C-H bond activation.钴催化的通过螯合辅助 C-H 键活化的炔烃的加氢芳基化反应。
J Am Chem Soc. 2010 Sep 8;132(35):12249-51. doi: 10.1021/ja106814p.
8
Synthesis of Cp-Re complexes via olefinic C-H activation and successive formation of cyclopentadienes.通过烯烃C-H活化和环戊二烯的连续形成来合成Cp-Re配合物。
J Am Chem Soc. 2008 Oct 29;130(43):14062-3. doi: 10.1021/ja805921f. Epub 2008 Oct 1.
9
Cobalt-catalyzed intermolecular C-H amination with bromamine-T as nitrene source.以溴胺-T作为氮烯源的钴催化分子间C-H胺化反应。
Chem Commun (Camb). 2007 Nov 28(44):4644-6. doi: 10.1039/b710677g. Epub 2007 Sep 3.
10
Cobalt-catalyzed ortho alkylation of aromatic imines with primary and secondary alkyl halides.钴催化的芳基亚胺与伯卤代烷和仲卤代烷的邻位烷基化反应。
J Am Chem Soc. 2013 Jun 26;135(25):9279-82. doi: 10.1021/ja403759x. Epub 2013 Jun 17.

引用本文的文献

1
C-H Activation and Sequential Addition to Dienes and Imines: Synthesis of Amines with -Quaternary Centers and Mechanistic Studies on the Complex Interplay Between the Catalyst and Three Reactants.碳-氢活化与二烯和亚胺的顺序加成：含季碳中心胺的合成及催化剂与三种反应物之间复杂相互作用的机理研究
ACS Catal. 2024 Dec 6;14(23):18124-18133. doi: 10.1021/acscatal.4c05866. Epub 2024 Nov 22.
2
Bidirectional Electron Transfer Strategies for Anti-Markovnikov Olefin Aminofunctionalization via Arylamine Radicals.通过芳基胺自由基实现反马氏烯烃氨基官能化的双向电子转移策略
ACS Catal. 2024 Aug 17;14(17):13156-13162. doi: 10.1021/acscatal.4c04110. eCollection 2024 Sep 6.
3
The crucial role of silver(I)-salts as additives in C-H activation reactions: overall analysis of their versatility and applicability.
银（I）盐在C-H活化反应中作为添加剂的关键作用：对其通用性和适用性的全面分析。
Chem Soc Rev. 2023 Sep 18;52(18):6359-6378. doi: 10.1039/d3cs00328k.
4
Transition-Metal-Catalyzed C-H Bond Activation for the Formation of C-C Bonds in Complex Molecules.过渡金属催化的 C-H 键活化在复杂分子中 C-C 键的形成。
Chem Rev. 2023 Jun 28;123(12):7692-7760. doi: 10.1021/acs.chemrev.2c00888. Epub 2023 May 10.
5
Cobalt(III)-catalyzed asymmetric ring-opening of 7-oxabenzonorbornadienes via indole C-H functionalization.钴(III)催化的通过吲哚 C-H 官能化的 7-氧杂苯并降冰片二烯的不对称开环反应。
Nat Commun. 2023 Feb 25;14(1):1094. doi: 10.1038/s41467-023-36723-6.
6
Cobalt(iii)-catalyzed site-selective C-H amidation of pyridones and isoquinolones.钴（III）催化吡啶酮和异喹啉酮的位点选择性C-H酰胺化反应。
RSC Adv. 2018 Sep 21;8(57):32659-32663. doi: 10.1039/c8ra06716c. eCollection 2018 Sep 18.
7
Co-catalyzed -C-H functionalization/annulation of arenes and alkenes with alkynylsilanes: access to isoquinolone and pyridone motifs.芳烃和烯烃与炔基硅烷的共催化-C-H官能化/环化反应：通向异喹啉酮和吡啶酮结构单元的途径
RSC Adv. 2019 Sep 26;9(53):30650-30654. doi: 10.1039/c9ra06963a.
8
Mapping Catalyst-Solvent Interplay in Competing Carboamination/Cyclopropanation Reactions.在竞争的碳氨化/环丙烷化反应中映射催化剂-溶剂相互作用。
Chemistry. 2022 Jul 20;28(41):e202200399. doi: 10.1002/chem.202200399. Epub 2022 Jun 10.
9
Monoallylation and benzylation of dicarbonyl compounds with alcohols catalysed by a cationic cobalt(iii) compound.由阳离子钴（III）化合物催化的二羰基化合物与醇的单烯丙基化和苄基化反应
RSC Adv. 2021 Mar 1;11(16):9235-9245. doi: 10.1039/d0ra09778k.
10
Stereoselective Synthesis of Allenyl Alcohols by Cobalt(III)-Catalyzed Sequential C-H Bond Addition to 1,3-Enynes and Aldehydes.钴(III)催化的 1,3-烯炔与醛的顺序 C-H 键加成反应立体选择性合成烯丙醇。
Angew Chem Int Ed Engl. 2022 Jun 20;61(25):e202202364. doi: 10.1002/anie.202202364. Epub 2022 Apr 29.