在常温条件下，通过金纳米粒子在 ZnO 上的等离子体介导催化作用，快速一锅法合成炔丙胺。
Rapid one-pot propargylamine synthesis by plasmon mediated catalysis with gold nanoparticles on ZnO under ambient conditions.
机构信息
Department of Chemistry and Centre for Catalysis Research and Innovation, University of Ottawa, Ottawa, Ontario K1N 5N6, Canada.
出版信息
Chem Commun (Camb). 2013 Feb 28;49(17):1732-4. doi: 10.1039/c3cc38287g.
PMID:23340772
Abstract
Surface plasmon excitation of gold nanoparticles on ZnO in the presence of an aldehyde, an amine and phenylacetylene led to rapid and selective formation of propargylamines with good yields (50-95%) at room temperature. Plasmon mediated catalysis is the best available route for this ternary coupling.
摘要
在醛、胺和苯乙炔存在的情况下，金纳米粒子在 ZnO 上的表面等离子体激发导致炔丙胺的快速和选择性形成，在室温下产率良好（50-95%）。等离子体介导的催化是这种三元偶联的最佳途径。
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