Institute of Nanotechnology, Karlsruhe Institute of Technology (KIT), Hermann-von-Helmholtz-Platz 1, D-76344 Eggenstein-Leopoldshafen, Germany.
Chem Soc Rev. 2013 Sep 21;42(18):7507-20. doi: 10.1039/c2cs35462d.
Technological and scientific challenges coupled with environmental considerations have prompted a search for simple and energy-efficient syntheses and processing routes of materials. This tutorial review provides an overview of recent research efforts in non-conventional reactions and syntheses of oxides induced by mechanical action. It starts with a brief account of the history of mechanochemistry. Ensuing discussions will review the progress in homogeneous and heterogeneous mechanochemical reactions in oxides of various structures. The review demonstrates that the event of mechanically induced reactions provides novel opportunities for the non-thermal manipulation of materials and for the tailoring of their properties.
技术和科学挑战以及环境考虑促使人们寻找简单且节能的材料合成和加工方法。本综述介绍了机械作用诱导的氧化物非常规反应和合成的最新研究进展。它首先简要介绍了机械化学的历史。随后的讨论将回顾各种结构的氧化物中均相和多相机械化学反应的进展。该综述表明，机械诱导反应的发生为非热材料处理和定制材料性能提供了新的机会。
