Institute of Geotechnics, Slovak Academy of Sciences, Watsonova 45, 04353, Košice, Slovakia.
Chem Soc Rev. 2013 Sep 21;42(18):7571-637. doi: 10.1039/c3cs35468g. Epub 2013 Apr 4.
The aim of this review article on recent developments of mechanochemistry (nowadays established as a part of chemistry) is to provide a comprehensive overview of advances achieved in the field of atomistic processes, phase transformations, simple and multicomponent nanosystems and peculiarities of mechanochemical reactions. Industrial aspects with successful penetration into fields like materials engineering, heterogeneous catalysis and extractive metallurgy are also reviewed. The hallmarks of mechanochemistry include influencing reactivity of solids by the presence of solid-state defects, interphases and relaxation phenomena, enabling processes to take place under non-equilibrium conditions, creating a well-crystallized core of nanoparticles with disordered near-surface shell regions and performing simple dry time-convenient one-step syntheses. Underlying these hallmarks are technological consequences like preparing new nanomaterials with the desired properties or producing these materials in a reproducible way with high yield and under simple and easy operating conditions. The last but not least hallmark is enabling work under environmentally friendly and essentially waste-free conditions (822 references).
这篇关于机械化学（如今已成为化学的一部分）最新进展的综述文章旨在全面概述原子过程、相转变、简单和多组分纳米系统以及机械化学反应特性方面所取得的进展。还回顾了在材料工程、多相催化和浸出冶金等领域成功渗透的工业方面。机械化学的特点包括通过固溶体缺陷、界面和弛豫现象影响固体的反应性，使过程在非平衡条件下进行，在结晶良好的纳米颗粒核心周围形成无序的近表面壳层区域，并进行简单、方便的干时间一步合成。这些特点带来的技术后果包括用所需的性质制备新的纳米材料，或者以高产率、简单和容易的操作条件下以可重复的方式生产这些材料。最后但同样重要的是，机械化学能够在环保且基本上无废物的条件下进行工作（引用 822 次）。
