School of Materials Science and Engineering, Georgia Institute of Technology, Atlanta, GA, USA.
Angew Chem Int Ed Engl. 2013 Apr 22;52(17):4618-22. doi: 10.1002/anie.201209141. Epub 2013 Jan 31.
Confined ions: The high penetrating power and sensitivity of neutron scattering to isotope substitution are harnessed to observe changes in the ion concentration in a porous carbon material as a function of the applied potential and the pore size. Depending on the solvent properties and the solvent-pore-wall interactions, either enhanced or reduced ion electroadsorption may take place.
中子散射对同位素取代的高穿透能力和灵敏度被利用来观察多孔碳材料中离子浓度随外加电势和孔径的变化。根据溶剂性质和溶剂-孔壁相互作用,可能会发生增强或减弱的离子电吸附。