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采用 Stöber 方法扩展制备介孔 SiO2 和 TiO2 壳,用于构建均匀的多功能核壳结构。

Extension of the Stöber method to construct mesoporous SiO2 and TiO2 shells for uniform multifunctional core-shell structures.

机构信息

Department of Chemistry, Fudan University, Shanghai, PR China.

出版信息

Adv Mater. 2013 Jan 4;25(1):142-9. doi: 10.1002/adma.201203547.

Abstract

Core–shell nanoparticles (CSNs) have attracted considerable attention because of their promising applications in a wide range of fields. Recently, substantial efforts have been focused on the development of facile and versatile methods for preparing CSNs with mesoporous SiO(2) or TiO(2) shells because of their fascinating properties, such as high surface area, large pore channels and high pore volume. This Research News reviews the recent progress in facile, versatile and reproducible approaches which are simply extended from the well-known Stöber method to construct mesoporous SiO(2) and TiO(2) shells for uniform multifunctional core–shell nanostructures. Several strategies, including the surfactant-templating process, the long-chain organosilane-assisted approach, the phase transfer assisted surfactant-templating process, and the kinetics-controlled coating approach, are discussed. In addition, new trends in this field for the creation of multifunctional CSNs and novel nanostructures are highlighted.

摘要

核壳纳米粒子(CSNs)由于其在广泛领域中的应用前景而受到极大关注。最近,由于具有迷人的特性,如高比表面积、大孔道和高孔体积,人们致力于开发简便且多功能的方法来制备具有介孔 SiO(2)或 TiO(2)壳的 CSNs。这篇研究新闻综述了简便、多功能且可重复的方法的最新进展,这些方法简单地从著名的 Stöber 方法扩展而来,用于构建用于均匀多功能核壳纳米结构的介孔 SiO(2)和 TiO(2)壳。讨论了几种策略,包括表面活性剂模板法、长链有机硅烷辅助法、相转移辅助表面活性剂模板法和动力学控制涂层法。此外,还强调了该领域用于创建多功能 CSNs 和新型纳米结构的新趋势。

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