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预组织水凝胶:通过含有环糊精和疏水客体基团的主体 - 客体单体聚合形成的超分子水凝胶的自修复特性。

Preorganized hydrogel: self-healing properties of supramolecular hydrogels formed by polymerization of host-guest-monomers that contain cyclodextrins and hydrophobic guest groups.

机构信息

Department of Macromolecular Science, Graduate School of Science, Osaka University, Toyonaka, Osaka, Japan.

出版信息

Adv Mater. 2013 May 28;25(20):2849-53. doi: 10.1002/adma.201205321. Epub 2013 Feb 19.

DOI:10.1002/adma.201205321
PMID:23423947
Abstract

Supramolecular hydrogels formed by a host-guest interaction show self-healing properties. The cube-shaped hydrogels with β-cyclodextrin and adamantane guest molecules mend after being broken. The hydrogels sufficiently heal to form a single gel, and the initial strength is restored. Although contact between a freshly cut and uncut surface does not mend the gels, two freshly cut surfaces selectively mend.

摘要

超分子水凝胶通过主客体相互作用形成,表现出自愈特性。具有β-环糊精和金刚烷客体分子的立方体形水凝胶在破裂后能够自我修复。水凝胶充分愈合后形成单个凝胶,初始强度得以恢复。虽然新鲜切割面和未切割面之间的接触不会使凝胶愈合,但两个新鲜切割面可以选择性地愈合。

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