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双[μ-4-(4-羧基苯氧基)邻苯二甲酸根合]双[三水合钴(II)]

Bis[μ-4-(4-carb-oxy-phen-oxy)phthalato]bis-[triaqua-cobalt(II)].

作者信息

Wang Liang

机构信息

Department of Chemistry, University of Science and Technology Beijing, Beijing 100083, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2013 Feb 1;69(Pt 2):m101. doi: 10.1107/S1600536813000536. Epub 2013 Jan 12.

DOI:10.1107/S1600536813000536
PMID:23424399
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3569198/
Abstract

The dinuclear title complex, [Co(2)(C(15)H(8)O(7))(2)(H(2)O)(6)], lies across an inversion center. The unique Co(II) ion is coordinated in a slightly distorted octa-hedral coordination geometry by two O atoms from a chelating 4-(carb-oxy-phen-oxy)phthalate ligand, three water O atoms and a further O atom from a bridging carboxyl-ate group of a symmetry-related 4-(carb-oxy-phen-oxy)phthalate ligand. In the crystal, O-H⋯O hydrogen bonds link the mol-ecules into a three-dimensional network.

摘要

双核标题配合物[Co₂(C₁₅H₈O₇)₂(H₂O)₆]位于一个对称中心上。独特的Co(II)离子通过来自螯合的4-(羧基苯氧基)邻苯二甲酸酯配体的两个O原子、三个水分子O原子以及来自一个对称相关的4-(羧基苯氧基)邻苯二甲酸酯配体的桥连羧酸根基团的另一个O原子，以稍有畸变的八面体配位几何构型配位。在晶体中，O—H⋯O氢键将分子连接成三维网络。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e441/3569198/cdb3cacb3788/e-69-0m101-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e441/3569198/fe81d33a71de/e-69-0m101-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e441/3569198/cdb3cacb3788/e-69-0m101-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e441/3569198/fe81d33a71de/e-69-0m101-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e441/3569198/cdb3cacb3788/e-69-0m101-fig2.jpg

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本文引用的文献

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