School of Chemistry, University of Nottingham, England, UK NG7 2RD.
Chem Commun (Camb). 2013 Apr 7;49(27):2759-61. doi: 10.1039/c3cc40452h.
We report here a new catalytic reaction in which, para-nitro azides are acylated by aldehydes to produce amides and molecular nitrogen in a single step. The transformation is believed to proceed via an electron transfer process mediated by the tert-butoxide ion, and catalysed by a thiazolium salt derived species.
我们在这里报告了一个新的催化反应，其中邻硝基叠氮化物被醛酰化，一步即可生成酰胺和氮气。据信，该转化是通过叔丁氧基离子介导的电子转移过程进行的，并由噻唑鎓盐衍生的物种催化。
