氯代{N - [(二乙氨基)-二甲基硅基]苯胺基-κN}(N,N,N',N'-四甲基乙烷-1,2-二胺-κ(2) N,N')铁(II)
Chlorido{N-[(diethyl-amino)-dimethyl-sil-yl]anilido-κN}(N,N,N',N'-tetra-methyl-ethane-1,2-diamine-κ(2) N,N')iron(II).
作者信息
Chen Juan
机构信息
Department of Chemistry, Taiyuan Teachers College, Taiyuan 030031, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2012 Dec 1;68(Pt 12):m1444. doi: 10.1107/S1600536812044741. Epub 2012 Nov 3.
In the title iron(II) complex, [Fe(C12H21N2Si)Cl(C6H16N2)], the Fe(II) cation is coordinated by two N atoms from the tetramethylethane-1,2-diamine ligand [Fe-N = 2.191 (5) and 2.215 (4) Å], one N atom from the N-[(diethyl-amino)-dimethyl-sil-yl]anilide ligand [Fe-N = 1.943 (4) Å] and a chloride ligand [Fe-Cl = 2.2798 (16) Å] in a distorted tetra-hedral geometry. The N-Si-N angle is 113.9 (3)°. The crystal packing exhibits no short inter-molecular contacts.
在标题化合物铁（II）配合物[Fe(C₁₂H₂₁N₂Si)Cl(C₆H₁₆N₂)]中，Fe（II）阳离子由四甲基乙烷 - 1,2 - 二胺配体中的两个N原子配位[Fe - N = 2.191（5）和2.215（4）Å]，N - [(二乙氨基) - 二甲基硅基]苯胺配体中的一个N原子[Fe - N = 1.943（4）Å]以及一个氯配体[Fe - Cl = 2.2798（16）Å]，呈扭曲的四面体几何构型。N - Si - N角为113.9（3）°。晶体堆积中不存在短程分子间接触。
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