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二氯双{ N -[(二甲基氨基)二甲基甲硅烷基]-2,6 -二甲基苯甲酰胺基-κN,N'}铁(III)

Chloridobis{N-[(dimethyl-amino)dimethyl-silyl]-2,6-dimethyl-anilido-κN,N'}iron(III).

作者信息

Chen Juan

机构信息

Department of Chemistry, Taiyuan Normal University, Taiyuan 030031, People's Republic of China.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2008 Jun 19;64(Pt 7):m938. doi: 10.1107/S1600536808018114.

DOI:10.1107/S1600536808018114
PMID:21202791
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2961661/
Abstract

The title iron(III) compound, [Fe(C(12)H(21)N(2)Si)(2)Cl], is monomeric. The Fe atom is N,N'-chelated by the N-silylated anilide ligand. The two ligands around the Fe atom are arranged trans to each other. The Fe-N(amino) bond is longer than the Fe-N(anilide) bond by about 0.37 Å. The mol-ecule displays a pseudo-twofold rotation. The five-coordinate Fe atom demonstrates a highly distorted trigonal-bipyramidal geometry.

摘要

标题铁（III）化合物[Fe(C₁₂H₂₁N₂Si)₂Cl]为单体。铁原子被N-硅烷基化苯胺配体进行N，N'-螯合。铁原子周围的两个配体彼此呈反式排列。Fe-N（氨基）键比Fe-N（苯胺）键长约0.37 Å。该分子呈现出假二重旋转对称性。五配位的铁原子展现出高度扭曲的三角双锥几何构型。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/130b/2961661/dcda50c99dcc/e-64-0m938-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/130b/2961661/dcda50c99dcc/e-64-0m938-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/130b/2961661/dcda50c99dcc/e-64-0m938-fig1.jpg

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Facile ring opening of iron(III) and iron(II) complexes of meso-amino-octaethylporphyrin by dioxygen.中-氨基-八乙基卟啉的铁（III）和铁（II）配合物被双氧 facile 开环。
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双[μ-N-（二乙氨基-κN）二甲基硅烷基苯胺基-κN:N]双[氯化钴（II）]
Acta Crystallogr Sect E Struct Rep Online. 2012 Jan;68(Pt 1):m81. doi: 10.1107/S1600536811054602. Epub 2011 Dec 23.
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Chloridobis{N-[(dimethyl-amino)-dimethyl-sil-yl]-2,6-dimethyl-anilido-κN,N'}titanium(III).
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6
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