二氯双{ N -[(二甲基氨基)二甲基甲硅烷基]-2,6 -二甲基苯甲酰胺基-κN,N'}铁(III)
Chloridobis{N-[(dimethyl-amino)dimethyl-silyl]-2,6-dimethyl-anilido-κN,N'}iron(III).
作者信息
Chen Juan
机构信息
Department of Chemistry, Taiyuan Normal University, Taiyuan 030031, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2008 Jun 19;64(Pt 7):m938. doi: 10.1107/S1600536808018114.
The title iron(III) compound, [Fe(C(12)H(21)N(2)Si)(2)Cl], is monomeric. The Fe atom is N,N'-chelated by the N-silylated anilide ligand. The two ligands around the Fe atom are arranged trans to each other. The Fe-N(amino) bond is longer than the Fe-N(anilide) bond by about 0.37 Å. The mol-ecule displays a pseudo-twofold rotation. The five-coordinate Fe atom demonstrates a highly distorted trigonal-bipyramidal geometry.
标题铁（III）化合物[Fe(C₁₂H₂₁N₂Si)₂Cl]为单体。铁原子被N-硅烷基化苯胺配体进行N，N'-螯合。铁原子周围的两个配体彼此呈反式排列。Fe-N（氨基）键比Fe-N（苯胺）键长约0.37 Å。该分子呈现出假二重旋转对称性。五配位的铁原子展现出高度扭曲的三角双锥几何构型。
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