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顺式-双{（E）-2-[(2-氟苯基)亚氨基甲基]苯酚根-κ(2) N,O}-双（吡啶-κN）镍（II）

cis-Bis{(E)-2-[(2-fluoro-phen-yl)imino-meth-yl]phenolato-κ(2) N,O}bis-(pyridine-κN)nickel(II).

作者信息

Souza Marcela C G, Ferreira Leonardo da C, Comerlato Nadia M, Ferreira Glaucio B, Visentin Lorenzo do Canto

机构信息

Instituto de Química, Universidade Federal do Rio de Janeiro, 21949-900 Rio de Janeiro, RJ, Brazil.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Dec 1;68(Pt 12):m1470. doi: 10.1107/S1600536812045576. Epub 2012 Nov 10.

DOI:10.1107/S1600536812045576
PMID:23468697
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3588732/
Abstract

The structure of the title compound, [Ni(C13H9FNO)2(C5H5N)2], consists of an Ni(II) atom on a crystallographic center of symmetry, octa-hedrally bonded through both the N and O atoms to two 2-[(2-fluoro-phen-yl)imino-meth-yl]phenolate (L) ligands, as well as two pyridine ligands. The F atoms of L are disordered over two positions related by a 180° rotation of the fluoro-phenyl group around its external C-N bond.

摘要

标题化合物[Ni(C₁₃H₉FNO)₂(C₅H₅N)₂]的结构由一个位于晶体学对称中心的Ni(II)原子组成，该原子通过N和O原子以八面体方式与两个2-[(2-氟苯基)亚氨基甲基]苯酚盐（L）配体以及两个吡啶配体键合。L配体中的F原子在两个位置上无序分布，这两个位置通过氟苯基围绕其外部C-N键旋转180°相关。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f01/3588732/dac1a16eb075/e-68-m1470-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f01/3588732/dac1a16eb075/e-68-m1470-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f01/3588732/dac1a16eb075/e-68-m1470-fig1.jpg

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本文引用的文献

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Acta Crystallogr Sect E Struct Rep Online. 2009 Jan 28;65(Pt 2):m231. doi: 10.1107/S160053680900244X.
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2,4-Di-tert-butyl-6-[(2,5-difluorophenyl)iminomethyl]phenol.2,4-二叔丁基-6-[(2,5-二氟苯基)亚氨基甲基]苯酚
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Three (E)-2-[(bromophenyl)iminomethyl]-4-methoxyphenols.三种（E）-2-[(溴苯基)亚氨基甲基]-4-甲氧基苯酚。
Acta Crystallogr C. 2007 Mar;63(Pt 3):o177-80. doi: 10.1107/S0108270107003241. Epub 2007 Feb 17.