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4-甲基-2,6-双（吡咯烷-1-基）嘧啶

4-Methyl-2,6-bis-(pyrrolidin-1-yl)pyrimidine.

作者信息

Sreenivasa S, Manojkumar K E, Shet Prakash M, Suchetan P A, Palakshamurthy B S

机构信息

Department of Studies and Research in Chemistry, Tumkur University, Tumkur, Karnataka 572 103, India.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2012 Dec 1;68(Pt 12):o3440. doi: 10.1107/S160053681204740X. Epub 2012 Nov 24.

DOI:10.1107/S160053681204740X
PMID:23476256
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3589020/
Abstract

In the crystal of the title compound, C13H20N4, the mol-ecule is nearly planar, the dihedral angles between the pyrimidine and the two pyrrolidine rings being 4.71 (2) and 4.50 (2)°. The crystal features inversion-related dimers linked by pairs of C-H⋯N hydrogen bonds generating R2(2)(16) patterns. The dimeric units are further linked into C(6) chains via an additional C-H⋯N hydrogen bond.

摘要

在标题化合物C₁₃H₂₀N₄的晶体中，分子近乎平面，嘧啶环与两个吡咯烷环之间的二面角分别为4.71 (2)°和4.50 (2)°。晶体具有通过成对的C—H⋯N氢键连接的与反演相关的二聚体，形成R2(2)(16)模式。二聚单元通过额外的C—H⋯N氢键进一步连接成C(6)链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6b2b/3589020/ce4b09b5f854/e-68-o3440-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6b2b/3589020/29fde310438a/e-68-o3440-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6b2b/3589020/ce4b09b5f854/e-68-o3440-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6b2b/3589020/29fde310438a/e-68-o3440-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6b2b/3589020/ce4b09b5f854/e-68-o3440-fig2.jpg

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