[2,6-Bis(5-eth-oxy-1,3-oxazol-2-yl)-4-meth-oxy-phenyl-κ(3) N,C (1),N']bromidopalladium(II).
作者信息
Nan Wen-Hui, Tan Jian-Ping, Luo Qun-Li
机构信息
Key Laboratory of Applied Chemistry of Chongqing Municipality, College of Chemistry and Chemical Engineering, Southwest University, Chongqing 400715, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2013 Jan 1;69(Pt 1):m31-2. doi: 10.1107/S1600536812049197. Epub 2012 Dec 8.
Abstract
In the title compound, [PdBr(C17H17N2O5)], the Pd(II) atom is coordinated by an N,C(1),N'-tridentate pincer ligand and a Br atom in a distorted square-planar geometry. In the crystal, mol-ecules are connected by C-H⋯Br and C-H⋯O hydrogen bonds, and π-π inter-actions between the oxazole and benzene rings [centroid-centroid distance = 3.7344 (19) Å], resulting in a three-dimensional supra-molecular structure.
摘要
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