THz QCL-based cryogen-free spectrometer for in situ trace gas sensing.

We report on a set of high-sensitivity terahertz spectroscopy experiments making use of QCLs to detect rotational molecular transitions in the far-infrared. We demonstrate that using a compact and transportable cryogen-free setup, based on a quantum cascade laser in a closed-cycle Stirling cryostat, and pyroelectric detectors, a considerable improvement in sensitivity can be obtained by implementing a wavelength modulation spectroscopy technique. Indeed, we show that the sensitivity of methanol vapour detection can be improved by a factor ≈ 4 with respect to standard direct absorption approaches, offering perspectives for high sensitivity detection of a number of chemical compounds across the far-infrared spectral range.